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1Increasing adoption of downsized, boosted, spark-ignition engines has improved vehicle fuel economy, and continued improvement is desirable to reduce carbon emissions in the near-term. However, this strategy is limited by damaging preignition events which can cause hardware failure. Research to date has shed light on various contributing factors related to fuel and lubricant properties as well as calibration strategies, but the causal factors behind an individual preignition cycle remain elusive. If actionable precursors could be identified, mitigation through active control strategies would be possible. This paper uses artificial neural networks to search for identifiable precursors in the cylinder pressure data from a large real-world data set containing many preignition cycles. It is found that while follow-up preignition cycles in clusters can be readily predicted, the initial preignition cycle is not predictable based on features of the cylinder pressure.

Heavy duty trucks account for about 50 percent of the NOx burden in urban areas and consume about 20 percent of the national transportation fuel in the United States. There is a continuing need to reduce emissions and fuel consumption. Much of the focus of current work is on engine development as a stand-alone subsystem. While this has yielded impressive gains so far, further improvement in emissions or engine efficiency is unlikely in a cost effective manner. Consequently, an integrated approach looking at the whole powertrain is required. A computer model of the heavy duty truck system was built and evaluated. The model includes both conventional and hybrid powertrains. It uses a series of interacting sub-models for the vehicle, transmission, engine, exhaust aftertreatment and braking energy recovery/storage devices. A specified driving cycle is used to calculate the power requirements at the wheels and energy flow and inefficiencies throughout the drivetrain.

An investigation was performed to determine the effects of applying on-highway heavy-duty diesel engine emissions reduction technology to an off-highway version of the engine. Special attention was paid to the typical constraints of fuel consumption, heat rejection, packaging and cost-effectiveness. The primary focus of the effort was NOx, reduction while hopefully not worsening other gaseous and particulate emissions. Hardware changes were limited to “bolt-on” items, thus excluding piston and combustion chamber modifications. In the final configuration, NOx was improved by 28 percent, particulates by 58 percent, CO and HC were also better and the fuel economy penalty was limited to under 4 percent. Observations are made about the effectiveness of various individual and combined strategies, and potential problems are identified.

Recent legislation, including the California Clean Air Act of 1988 and the Federal Clean Air Act Amendment of 1990, includes off-road engines, equipment, and vehicles as targets for new exhaust emissions regulations. The Santa Barbara County Air Pollution Control District in cooperation with EXXON USA is conducting a major Low NOx Demonstration Program including mobile sources, construction equipment, and offshore equipment. As a part of this program, an existing backhoe has been retrofitted with a low NOx engine and demonstrated in the field. This paper discusses the work performed to allow Case model 580 backhoes to be retrofitted with Cummins 4BTAA3.9 on-highway turbocharged diesel engines. A standard production conversion kit can be used to mount the new engines in place of the older existing JI Case engines in some models while other newer models already have 4B3.9 engines. In addition, an air-to-air aftercooler and associated plumbing was designed and installed.

When technologies are traded for incorporation into vehicle systems to support a specific mission scenario, they are often assessed in terms of “Technology Readiness Level” (TRL). TRL is based on three major categories of Core Technology Components, Ancillary Hardware and System Maturity, and Control and Control Integration. This paper describes the Technology Readiness Level assessment of the Carbon Dioxide Reduction Assembly (CRA) for use on the International Space Station. A team comprising of the NASA Johnson Space Center, Marshall Space Flight Center, Southwest Research Institute and Hamilton Sundstrand Space Systems International have been working on various aspects of the CRA to bring its TRL from 4/5 up to 6. This paper describes the work currently being done in the three major categories. Specific details are given on technology development of the Core Technology Components including the reactor, phase separator and CO2 compressor.

It is widely acknowledged that the CFR octane rating engines are not representative of modern engines and that there is a gap in the quantification of knock severity between the two engine types. As part of a comprehensive study of the autoignition of different fuels in both the CFR octane rating engines and a modern, direct injection, turbocharged spark-ignited engine, a series of fuel blends were tested with varying composition, octane numbers and ethanol blend levels. The paper reports on the fourth part of this study where cylinder pressures were recorded under standard knock conditions in CFR engines under RON and MON conditions using the ASTM prescribed instrumentation. By the appropriate signal conditioning of the D1 detonation pickups on the CFR engines, a quantification of the knock severity was possible that had the same frequency response as a cylinder pressure transducer.

Nitrous Oxide (N₂O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 (298-310 times more potent than carbon dioxide (CO₂)). As a result, any aftertreatment system that generates N₂O must be well understood to be used effectively. Under low temperature conditions, N₂O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N₂O formed by the thermal decomposition of ammonium nitrate. Ammonium nitrate and N₂O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO₂). This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO₂ ratio above 1. However, N₂O has also been observed at relatively high temperatures, in the region of 500°C.

Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.

With the conclusion of the California Air Resources Board (CARB) Stage 1 Ultra-Low NOX program, there continues to be a commitment for identifying potential pathways to demonstrate 0.02 g/hp-hr NOX emissions. The Stage 1 program focused on achieving the Ultra-Low NOX (ULN) levels utilizing a turbo-compound (TC) engine, which required the integration of novel catalyst technologies and a supplemental heat source. While the aftertreatment configuration provided a potential solution to meet the ULN target, a complicated approach was required to overcome challenges from low temperature exhaust. The Stage 3 program leverages a different engine architecture more representative of the broader heavy-duty industry to meet the Phase 2 Greenhouse Gas (GHG) targets and to simplify the ULN aftertreatment solution. The following work will discuss the aftertreatment technology evaluation, down selection criteria, and the emission results for the candidate ULN systems

Despite considerable progress over the last several decades, California continues to face some of the most significant air quality problems in the United States. These continued issues highlight the need for further mobile source NOX reductions to help California and other areas meet ambient air quality targets mandated by the U.S. EPA. Beginning in 2014, the California Air Resources Board (CARB) launched a program aimed at demonstrating technologies that could enable heavy-duty on-highway engines to reach tailpipe NOX levels up to 90% below the current standards, which were implemented in 2010. At the same time, mandated improvements to greenhouse gas emissions (GHG) require that these NOX reductions be achieved without sacrificing fuel consumption and increasing GHG emissions.

Off-road diesel engines remain one of the most significant contributors to the overall oxides of nitrogen (NOX) inventory and the California Air Resources Board (CARB) has indicated that reductions of up to 90% from current standards may be necessary to achieve its air quality goals. In recognition of this, CARB has funded a program aimed at demonstrating emission control technologies for off-road engines. This program builds on previous efforts to demonstrate Low NOX technologies for on-road engines. The objective was to demonstrate technologies to reduce tailpipe NOX and particulate matter (PM) emissions by 90 and 75%, respectively, from the current Tier 4 Final standards. In addition, the emission reductions were to be achieved while also demonstrating a 5 to 8.6% carbon dioxide (CO2) reduction and remaining Greenhouse Gas (GHG) neutral with respect to nitrous oxide (N2O) and methane (CH4).

The current operation of the International Space Station (ISS) calls for the oxygen used by the occupants to be vented overboard in the form of CO2, after the CO2 is scrubbed from the cabin air. Likewise, H2 produced via electrolysis in the oxygen generator is also vented. NASA is investigating the use of the Sabatier process to combine these two product streams to form water and methane. The water is then used in the oxygen generator, thereby conserving this valuable resource. One of the technical challenges to developing the Sabatier reactor is transferring CO2 from the Carbon Dioxide Removal Assembly (CDRA) to the Sabatier reactor at the required rate, even though the CDRA and the Sabatier reactor operate on different schedules. One possible way to transfer and store CO2 is to use a mechanical compressor and a storage tank.

An increasing number of passenger vehicle exhaust systems incorporate catalytic converters that are “close-coupled” to the exhaust manifold to further reduce the quantity of cold-start emissions and increase overall catalyst conversion efficiencies. In general, close-coupled catalytic converters are not necessarily subjected to higher inlet exhaust temperatures than conventional underbody catalytic converters. To establish a foundation of on-vehicle temperature data, several passenger vehicles with close-coupled catalytic converters were studied while operating on a chassis dynamometer. Converter temperatures were measured over a variety of vehicle test conditions, including accelerations and extended steady-state speeds for several throttle positions, at both zero- and four-percent simulated road grades.

In order to further reduce vehicle cold-start emissions, the use of catalytic converters that are “close-coupled” to the exhaust manifold is increasing. To understand the vibrational environment of close-coupled and underbody converters, a laboratory study was conducted on several passenger vehicles. Catalytic converter vibration spectra were measured on a chassis dynamometer with the vehicle operating over a variety of test conditions. Vehicle operating conditions included hard accelerations and extended steady-state speeds at distinct throttle positions over zero-percent and four-percent simulated road grades.

A theoretical model for predicting cetane number of primary reference fuels from parameters measurable by proton nuclear magnetic resonance is presented. This modeling technique is expanded to include secondary reference fuels, pure hydrocarbons, and commercial-type fuels. An evaluation of the ignition process indicated that not only hydrogen type distribution measurable by proton NMR, but also relative hydrogen population is important in predicting cetane number. Two mathematical models are developed. One predicts cetane number of saturate fuels and the second predicts cetane number of fuels containing aromatic components. The aromatic fuel model is tested using the ASTM Diesel Check Fuels and shown to predict within the standard error of the model.

Stringent emissions regulations and the need for lower tailpipe emissions are pushing the development of low-carbon alternative fuels. H2 is a zero-carbon fuel that has the potential to lower CO2 emissions from internal combustion engines (ICEs) significantly. Moreover, this fuel can be readily implemented in ICEs with minor modifications. Batteries can be argued to be a good zero tailpipe emission solution for the light-duty sector; however, medium and heavy-duty sectors are also in need of rapid decarbonization. Current strategies for H2 ICEs include modification of the existing spark ignition (SI) engines to run on port fuel injection (PFI) systems with minimal changes from the current compressed natural gas (CNG) engines. This H2 ICE strategy is limited by knock and pre-ignition. One solution is to run very lean (lambda >2), but this results in excessive boosting requirements and may result in high NOx under transient conditions.

Particle number concentrations and size distributions were measured for the diluted exhaust of a 1991 diesel engine during the US FTP transient cycle for heavy-duty diesel engines. The engine was operated on US 2-D on-highway diesel fuel. The particle measurement system consisted of a full flow dilution tunnel as the primary dilution stage, an air ejector pump as the secondary dilution stage, and an electrical low pressure impactor (ELPI) for particle size distribution measurements. Particle number emission rate was the highest during the Los Angeles Non Freeway (LANF) and the Los Angeles Freeway (LAF) segments of the transient cycle. However, on brake specific number basis the LAF had the lowest emission level. The particle size distribution was monomodal in shape with a mode between 0.084 μm and 0.14 μm. The shape of the size distribution suggested no presence of nanoparticles below the lower detection limit of the instrument (0.032 μm), except during engine idle.

The primary goal of this project was to characterize particulate emissions from a snowmobile engine through measurement of particulate matter volatile organic fraction (VOF), particle size, and biological activity. Emissions were evaluated using both a mineral oil and a biosynthetic oil. Basic criteria pollutants were also measured from diluted exhaust using conventional techniques. Particulate matter volatile organic fraction was determined using a gas chromatographic method (DFI/GC). Particle size was characterized using a scanning mobility particle sizer (SMPS), and particulate matter biological activity was measured using a modification of the Ames bioassay procedure. Results revealed that more than 99 percent of the particles were ultrafine (Dp<100nm), with a peak concentration in the nanoparticle (Dp<50nm) size range. It was also observed that the use of a biosynthetic lubricant increased both volatile and total PM mass emissions compared to the mineral lubricant.

The 2010 emission standards for heavy-duty diesel engines in the U.S. have established a limit for oxides of nitrogen (NOx) emissions of 0.20 g/bhp-hr., a 90% reduction from the previous emission standards. However, it has been projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with the 2010 emission standards, the upcoming National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and ozone will not be achieved in California without further significant reductions in NOx emissions from the heavy-duty vehicle fleet. Given this, there is potential of further reduction in NOx emissions limit standards for heavy duty engines in the US. Recently there have been extensive studies and publications focusing on ultra-low NOx after treatment technologies that help achieve up to 0.02g/bhp-hr. at tailpipe [1].

This paper describes the findings of a laboratory effort to demonstrate improved automotive exhaust emission control with a cold-start hydrocarbon collection system. The emission control strategy developed in this study incorporated a zeolite molecular sieve in the exhaust system to collect cold-start hydrocarbons for subsequent release to an active catalytic converter. A prototype emission control system was designed and tested on a gasoline-fueled vehicle. Continuous raw exhaust emission measurements upstream and downstream of the zeolite molecular sieve revealed collection, storage, and release of cold-start hydrocarbons. Federal Test Procedure (FTP) emission results show a 35 percent reduction in hydrocarbons emitted during the cold-transient segment (Bag 1) due to adsorption by the zeolite.